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1. chinaXiv:201703.00485 [pdf]

快速沉积与侵蚀对地温场及天然气水合物成藏演化的影响:以南海北部陆坡为例 Impacts of fast sedimentation and erosion on the evolution of geothermal field and gas hydrate system: cases of Northern South China Sea

张毅, 何丽娟, 汪集旸
Subjects: Geosciences >> Space Physics

海洋沉积物中天然气水合物的存在与分布与地温条件紧密相关。南海北部陆坡大部分区域更、全新世沉积速率较高,同时局部地区(如神狐天然气水合物钻探区)发育有大量的海底冲蚀谷。这些快速沉积或侵蚀作用可以对地温场及天然气水合物的形成与赋存产生重要影响,然而目前注意到这些问题的研究相对较少。本文中我们结合南海北部陆坡的实际情况,建立了针对地温场发生动态变化时的水合物成藏数值模型。我们给出两个成藏模拟案例,其一是快速沉积的情形,其二是地形遭受侵蚀、产生冲蚀谷时的情形。结果表明,在这两种情形下地温场将发生不同的瞬态调整,并对天然气水合物在地层中聚集及分布产状产生重要影响。在快速沉积发生时,地温梯度将变小,天然气水合物稳定带(HSZ)将增厚;然而当其底界将随着热传递而上升,天然气水合物将不断在原稳定带底界分解,而后在新的稳定带底界处重新生成水合物。这样长时间的快速沉积作用可以造成水合物主要富集在稳定带底界处。而当快速侵蚀作用发生时,地温梯度将变大,天然气水合物稳定带的厚度将变薄,原来位于冲蚀谷处的水合物藏将被侵蚀作用破坏。而后,随着热平衡的发展,逐渐形成新的、类似于似海底反射层的稳定带底界。单纯考虑甲烷扩散作用下,高丰度水合物的形成需要较长的时间,相对而言脊下的水合物成藏较好,形成矿点的概率较大。 The occurrence and distribution of gas hydrate in marine sediments is closely related to the state of geothermal field. The sedimentation rate is relatively high during the Pleistocene and Holocene in the northern margin of the South China Sea. Moreover, there are many erosional canyons at the sea bottom in some local areas. Such fast sedimentation and erosion can greatly affect the geothermal regime and the formation and occurrence of gas hydrate deposits. However, there are few studies that consider such scenarios. In this study, considering the geological reality, we build a numerical reservoir model aimed to simulate the evaluation of the gas hydrate system upon two cases: the fast sedimentation and the development of erosional canyons. The results indicate the geothermal filed and the accumulation and distribution of gas hydrate can be adjusted dynamically when the fast sedimentation or erosion occurs. Under fast sedimentation, the geothermal gradient becomes smaller and the thickness of gas hydrate stability zone (HSZ) becomes larger. However, due to the role of heat transfer, the bottom of HSZ rises upward. This process leads to the hydrate near the previous bottom of HSZ being dissociated and depositing near the bottom of new HSZ. After a long duration, the fast sedimentation will result the formation of hydrate being mainly enriched near the bottom of HSZ. By contrast, when fast erosion occurs, the geothermal gradient increases and the HSZ turn thinner. The gas hydrate deposit system can be partially destroyed by the formation of canyons. A long time is necessary for the recovery of a gas hydrate deposit with significant abundance. Relatively, the deposits under the residual ridges are more possible to be potential “sweet spots”.

submitted time 2017-03-23 Hits38580Downloads2918 Comment 0

2. chinaXiv:201703.01172 [pdf]

304不锈钢在淡化海水中的点蚀行为

高丽飞; 杜敏
Subjects: Materials Science >> Materials Science (General)

运用开路电位、交流阻抗、阳极极化曲线和电化学频率调制技术研究了304不锈钢在不同温度(60~90℃)及不同海水(一级反渗透淡化海水、天然海水、1.6倍浓缩海水)中的点蚀行为。结果表明,304不锈钢在一级反渗透淡化海水中随着温度的升高点蚀敏感性增加;在发生点蚀前的钝化状态下,304不锈钢在一级反渗透淡化海水中比在海水中腐蚀严重;304不锈钢的点蚀敏感性随Cl-浓度的升高而增加;304不锈钢在80℃下的一级反渗透淡化海水中随浸泡时间的延长,腐蚀速率逐渐增大,且在浸泡1d时即有发生点蚀的倾向,在第10d时已经发生了点蚀。

submitted time 2017-03-31 From cooperative journals:《腐蚀科学与防护技术》 Hits34372Downloads1208 Comment 0

3. chinaXiv:201611.00452 [pdf]

Na2MoO4–有机膦A复合缓蚀剂对55%LiBr中碳钢的缓蚀行为

李杰兰; 梁成浩; 黄乃宝
Subjects: Materials Science >> Materials Science (General)

本文采用失重法、电化学测试技术、原子力显微镜和电子探针显微分析等方法考察了Na2MoO4-有机膦A复合缓蚀剂对55%LiBr+0.07mol/L LiOH溶液中碳钢的缓蚀性能。结果表明,240℃时添加800mg/L Na2MoO4-有机膦A复合缓蚀剂的55%LiBr+0.07mol/L LiOH溶液中碳钢腐蚀速度为43.2μm/a。沸腾的55%LiBr+0.07mol/L LiOH溶液中添加该缓蚀剂后,碳钢的钝化电位区间拓宽,钝化电流密度降低,反应电阻Rt值显著增加,缓蚀效率可达94.4%。该缓蚀剂能使碳钢表面形成显微结构为孤岛状的膜层,主要成分为铁和钼的氧化物。

submitted time 2016-11-14 From cooperative journals:《中国腐蚀与防护学报》 Hits32869Downloads1027 Comment 0

4. chinaXiv:201703.01169 [pdf]

模拟海洋大气条件下直流电场作用对碳钢初期腐蚀行为的影响

林德源; 戴念维; 陈云翔; 倪清钊; 张鑫; 张俊喜
Subjects: Geosciences >> Marine Sciences

采用失重分析、极化曲线测试和SEM分析手段,研究了模拟海洋大气环境下直流电场对碳钢初期腐蚀行为的影响。结果表明,直流电场的存在加速了碳钢的初期腐蚀速率,但并没有改变其腐蚀动力学;直流电场存在有利于具有亚稳片状结构的γ-FeOOH的形成,同时抑制了γ-FeOOH向具有保护性能的α-FeOOH的转化,从而导致锈层的保护性能下降,加速了碳钢的腐蚀。

submitted time 2017-03-31 From cooperative journals:《腐蚀科学与防护技术》 Hits31432Downloads1886 Comment 0

5. chinaXiv:201611.00438 [pdf]

海水中带锈碳钢的腐蚀电化学行为及腐蚀速率测定

彭欣; 王佳; 王金龙; 山川; 贾红刚; 刘在健; 王海杰
Subjects: Materials Science >> Materials Science (General)

摘要:为了可靠测定和解析锈层下金属腐蚀电化学,分别利用失重法和电化学方法对海水中不同浸泡时间的碳钢电极的腐蚀行为和腐蚀速率规律进行了研究。发现对于长期浸泡的碳钢电极,失重法和电化学方法得到的腐蚀速率结果见存在很大差异。利用XRD测定了长期浸泡后锈层成分的变化,发现长期浸泡碳钢电极锈层中的电化学活性成分β-FeOOH在测试过程中发生还原反应导致利用电化学方法测得的碳钢腐蚀速率大于失重法的结果,并且随浸泡时间的延长,这一偏差也增大。对长期浸泡碳钢电极进行-25μA/cm2阴极恒电流预极化处理后发现,随着浸泡时间的延长极化时间也延长,同时,经过预处理之后的碳钢电极电化学方法测得的腐蚀速率与失重法的结果间具有一致的变化规律,能够减小电化学方法对失重法测试结果的偏差。

submitted time 2016-11-14 From cooperative journals:《中国腐蚀与防护学报》 Hits30406Downloads1193 Comment 0

6. chinaXiv:201704.00121 [pdf]

聚酯表面类金刚石薄膜的制备及疏水性能

孙丽丽; 郭鹏; 李晓伟; 柯培玲; 汪爱英
Subjects: Geosciences >> Marine Sciences

采用线性离子束技术在 PET 基材表面制备类金刚石薄膜,分析薄膜结构、性能随离子束电流的演变规律 并研究了薄膜润湿特性与表面形貌、结构、表面能的作用关系。结果表明:沉积在 PET 表面的类金刚石薄膜具 有典型的非晶碳膜结构特征,随着离子束电流的增大 sp2/sp3 比值由 0.774 增加到 1.622,薄膜表面的石墨化程度 提高;改性后的 PET 材料接触角从 63.51°增大到 103.7°。进一步分析发现,疏水性能的提高归因于材料表面能 的降低,表面石墨化程度的提高和微-纳结构的形成是表面能降低的根本原因。此外,疏水的 PET 材料在 500~ 760 nm可见光范围内具有一定的増透效果,透过率达到88.5%以上。用线性离子束沉积碳膜及刻蚀技术能得 到合适的微观形貌和表面化学结构,可在保持基体材料透明性的同时提高 PET 柔性聚合物材料的疏水性能。

submitted time 2017-04-10 From cooperative journals:《材料研究学报》 Hits30293Downloads1577 Comment 0

7. chinaXiv:201904.00091 [pdf]

Dynamics of infiltration rate and Field-Saturated soil hydraulic conductivity in a Wastewater-Irrigated cropland

Siyi Zhang; Isaac Hopkins; Li Guo; Henry Lin
Subjects: Geosciences >> Geography

The maintenance of a soil’s infiltration rate (IR) and field-saturated hydraulic conductivity (Kfs) is crucial for the long-term sustainable functioning of wastewater-irrigated lands. However, an effective procedure for reliably measuring in situ soil Kfs remains elusive. To address this issue, this study investigated the DualHead Infiltrometer (DHI), a novel instrument for automatically determining IR and Kfs, and compared it with a traditional Double-Ring Infiltrometer (DRI) under various field conditions. In the initial phase, we optimized the procedure and settings for the DHIs in a cropland that has been spray-irrigated with secondary-treated wastewater for decades in central Pennsylvania. Results showed that our optimized procedure, which used a single, long pressure cycle, yielded more robust measurements of IR than the originally recommended sequence of two short pressure cycles. The values of Kfs measured by the DHIs with optimized settings were similar to those measured by DRIs under many (but not all) field conditions, due to their differences in infiltration surface areas, operational procedures, length of infiltration time, and soil spatiotemporal variability. Viscosity-corrected Kfs on the irrigated cropland was 123.8±94.0 mm h-1, higher than that on the adjacent non-irrigated cropland (103.2±94.6 mm h-1), but the difference was not statistically significant, owing to the high degree of soil spatiotemporal variability and our limited number of measurements. Nevertheless, the higher Kfs values measured on irrigated cropland reflect observed changes in soil structure (e.g., soil pore characteristics) that have resulted from decades of irrigation. Seasonal variations in Kfs values existed between winter and summer conditions, but IRs during all seasons remained much higher than the current spray-irrigation rate (4.25 mm h-1), suggesting that the soil is still capable of handling the routine irrigation, even during winter. However, the coefficients of variation exceeded 67.0% across the field sites investigated and the time periods covered by our measurements were limited. As this specific site is permitted to discharge treated wastewater year-round, caution must still be exercised to ensure that soil Kfs remains high enough to prevent runoff generation, especially during winter frozen conditions.

submitted time 2019-09-06 Hits24433Downloads1665 Comment 0

8. chinaXiv:201703.00311 [pdf]

Deep space communication channel characteristics under solar scintillation

Wu, Tong; Yan, Yi; Li, Yongcheng; Wang, Chunmei; Yao, Xiujuan; Li, Xue
Subjects: Geosciences >> Space Physics

Electromagnetic waves used for deep space communications are mainly affected by the charged particles ejected by the sun. These effects may result in degradation of communication quality or communication interruption. This paper discusses the effects of solar scintillation on electro-magnetic waves, including the scintillation index which is a measure of the intensity scintillation, the coherence bandwidth and the coherence time of deep space communication channel. The deep space communication channel under solar scintillation is modeled by using Rician fading channel according to the scintillation index. The coherence bandwidth will determine whether the channel is flat fading or frequency selective fading and the coherence time will determine whether the channel is slow fading or fast fading. The approach of choosing signal band width is determined by the coherence bandwidth and the coherence time with the change of the solar elongation angle. The simulation results show the bit error rate of the signal bandwidth chosen by the proposed approach is lower than a random choice.

submitted time 2017-03-10 Hits21695Downloads1699 Comment 0

9. chinaXiv:201703.01177 [pdf]

Radial variations of outward and inward Alfvnic fluctuations based on Ulysses observations

Yang, L.; Lee, L. C.; Li, J. P.; Luo, Q. Y.; Kuo, C. L.; Shi, J. K.; Wu, D. J.
Subjects: Geosciences >> Space Physics

Ulysses magnetic and plasma data are used to study hourly-scale Alfv{\'e}nic fluctuations in the solar polar wind. The calculated energy ratio $R^2_{v_A}$(cal) of inward to outward Alfv{\'e}n waves is obtained from the observed Wal{\'e}n slope through an analytical expression, and the observed $R^2_{v_A}$(obs) is based on a direct decomposition of original Alfv{\'e}nic fluctuations into outward- and inward-propagating Alfv{\'e}n waves. The radial variation of $R^2_{v_A}$(cal) shows a monotonically increasing trend with heliocentric distance $r$, implying the increasing local generation or contribution of inward Alfv{\'e}n waves. The contribution is also shown by the radial increase in the occurrence of dominant inward fluctuations. We further pointed out a higher occurrence ($\sim 83\%$ of a day in average) of dominant outward Alfv{\'e}nic fluctuations in the solar wind than previously estimated. Since $R^2_{v_A}$(cal) is more accurate than $R^2_{v_A}$(obs) in the measurement of the energy ratio for dominant outward fluctuations, the values of $R^2_{v_A}$(cal) in our results are likely more realistic in the solar wind than previously estimated and than $R^2_{v_A}$(obs) in our results. The duration ratio $R_T$ of dominant inward to all Alfv{\'e}nic fluctuations increases monotonically with $r$, and is about two or more times that from {\it Voyager 2} observations at $r \geq 4$~AU. Finally, from the variation trend in our results, a higher (lower) occurrence rate is expected at $r < 1$~AU ($r > 4$~AU) for dominant outward Alfv{\'e}nic fluctuations, and opposite variations are expected for dominant inward fluctuations. Simultaneously, $R^2_{v_A}$(cal) and $R_T$ will be expected to be smaller at $r < 1$~AU and larger at $r > 4$~AU. These results reveal new qualitative and quantitative features of Alfv{\'e}nic fluctuations therein compared with previous studies and put constraints on modelling the variation of solar wind fluctuations.

submitted time 2017-03-31 Hits19427Downloads1217 Comment 0

10. chinaXiv:202001.00048 [pdf]

甘肃省土地利用空间协调度时空分异及态势分析

王全喜; 孙鹏举; 刘学录; 任君; 刘永康
Subjects: Geosciences >> Geography

以甘肃省土地开发强度与土地供给能力的协调关系为研究对象,运用指数计算模型、协调度模型和R/S分析方法研究了2001—2016年甘肃省土地利用空间协调度时空格局分异及态势,以期对国土开发利用、社会经济、资源环境相互协调推进提供参考依据。结果表明:(1) 甘肃省土地开发强度呈现上升趋势,土地供给能力变化幅度较小,基本保持在0.4左右。(2) 土地利用空间协调度时间上呈现上升—下降趋势,空间上呈现从河西走廊地区向陇东、陇南地区递增的空间格局,且河西地区土地利用空间协调状态不稳定,协调等级较低。(3) 各地区土地利用空间协调度的Hurst指数均大于0.5,在未来一段时间内土地利用空间协调度仍然会以延续过去变化态势为主,其中张掖市具有较强持续性,而其余地区持续性相对较弱。整体上,甘肃省土地利用空间协调度时空分异特征仍十分明显。为了满足将来土地开发利用的需求,各市州要明确发展定位,在资源环境约束下合理调控土地开发利用强度。

submitted time 2020-01-06 From cooperative journals:《干旱区地理》 Hits18417Downloads793 Comment 0

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